Ученые создали бетон с эффектом «молекулярного велькро», способный к многократному самовосстановлению трещин

*Important notice: This news reports on an unedited version of an accepted paper and is awaiting final editing. Therefore, the paper should not be regarded as conclusive or treated as established information.   Researchers have developed an innovative self-healing cement composite incorporating ultra-low concentrations of polymers that enable rapid, repeatable crack repair through reversible molecular interactions, significantly enhancing concrete durability without compromising its fundamental properties. Study: A molecular velcro self-healing cement. Image Credit: Surachet Jo/Shutterstock.com Challenges in Cement Durability Concrete is the most widely used construction material, yet its durability is fundamentally limited by cracking. Cement manufacturing has a substantial carbon footprint, accounting for 8-9% of global anthropogenic CO2 emissions, with production projected to increase. Improving concrete longevity through self-healing can reduce environmental impact by reducing maintenance needs and extending infrastructure service life. Traditional autogenous self-healing in concrete relies on continued hydration or carbonation, but this is limited and decreases with age. Existing self-healing strategies typically depend on encapsulated agents, vascular networks, or high concentrations of additives, which restrict scalability, repeatability, and mechanical performance. An alternative involves direct incorporation of polymers into the cement matrix to induce reversible molecular interactions for healing. However, prior approaches often require relatively high polymer loadings, impeding adoption. This study introduces a novel "molecular velcro" self-healing cement composite using ultra-low polymer content (<0.15 wt%) that autonomously heals multiple crack cycles with minimal impact on cement hydration, setting, or workability, offering a scalable path toward more durable concrete. Molecular Velcro Cement Synthesis The self-healing cement was synthesized by blending a complex of poly(acrylic acid) (PAA), poly(ethylene oxide) (PEO), and branched poly(ethylene imine) (bPEI) into a cementitious matrix consisting of Type I/II Portland cement and silica fume in a 7:3 weight ratio. Healing behavior was investigated by creating cracks and monitoring closure kinetics using high-resolution X-ray computed tomography (XCT) and optical microscopy. Polymer redistribution was characterized via time-resolved confocal Raman spectroscopy and identical-location scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM–EDS). Mechanical performance under multi-cycle loading and healing was assessed through compressive, tensile, and flexural tests using post-peak loading protocols inducing 20% strength loss beyond the maximum. Rheological, setting time, and hydration analyses were performed to evaluate effects on workability and cement chemistry. Solid-state nuclear magnetic resonance (NMR) spectroscopy and atomistic simulations complemented characterization to elucidate chemical interactions governing healing. Click here to download a free PDF copy of this page Polymer-Cement Healing Performance The study demonstrates that incorporating less than 0.15 wt% of the PAA/PEO/bPEI polymer complex forms an in-situ molecular network within the hydrated cement matrix that drives autonomous, repeatable self-healing. This network operates by reversible electrostatic and hydrogen bonding interactions, akin to molecular-scale "Velcro," which enable polymer chains to redistribute and rebind at fracture surfaces efficiently. XCT and optical microscopy reveal rapid crack sealing, including closure across fractures approximately 2 mm deep within roughly 4 hours, corresponding to healing rates near 10 mm per day. Raman spectroscopy exhibited bi-exponential kinetics with characteristic time constants around 10 minutes and 9 hours, reflecting two stages: fast polymer transport toward crack interfaces followed by slower interfacial reorganization and rebonding. SEM–EDS confirmed polymer accumulation at healed crack faces, with increased carbon signal and diminished calcium and silicon signals, indicating polymer coating without excessive hydration product formation. Mechanical testing under severe post-peak loading confirms robust strength recovery, with up to 62% compressive strength and 59% direct tensile strength restored after damage-healing cycles. Importantly, the polymer-cement composite sustained self-healing ability over six damage-healing cycles, surpassing previously reported systems where capacity declined after fewer cycles. The polymer concentration used was approximately one-eighth that of the lowest concentrations in other reported self-healing cements, minimizing disruption to cement hydration and setting times, as evidenced by only a 15-minute difference in Vicat setting times between control and polymer-modified samples. Rheological tests indicated minimal impact on workability. Characterization suggests that crack formation creates capillary and pressure gradients that actively draw polymer chains to fracture surfaces, where reversible electrostatic and hydrogen bonds mediate healing. Solid-state NMR and atomistic modeling further elucidate this interfacial bonding, highlighting specific interactions with calcium silicate hydrate phases. Healing efficacy does not depend on perfect alignment of crack faces, as new surfaces are coated and bonded by polymer redistribution. Implications for Sustainable Concrete This research develops a novel self-healing cement composite utilizing a molecular Velcro mechanism enabled by an ultra-low concentration polymer complex. The approach achieves rapid, autonomous crack closure and significant mechanical strength recovery across multiple damage-healing cycles without compromising cement hydration, setting, or workability. The polymer’s reversible electrostatic and hydrogen bonding interactions with both itself and cement hydration products facilitate efficient redistribution and rebonding at crack surfaces. The result is a scalable, economically viable pathway to extend concrete service life and reduce repair needs, aligning with sustainability goals by mitigating carbon emissions through longer-lasting infrastructure. The findings establish design principles emphasizing trace additive concentrations combined with intrinsic pore-scale transport to achieve durable, repeatable healing in cementitious materials. This work invites further industrial-scale validation to translate molecular engineering advances into resilient construction technologies. Journal Reference Zeng C., Li Z., et al. (2026). A molecular velcro self-healing cement. Nature Communications. DOI: 10.1038/s41467-026-76061-x, https://www.nature.com/articles/s41467-026-76061-x