Ученые Университета Кентукки превратили отходы бурбона в суперконденсаторы с энергоемкостью в 25 раз выше обычных

By pressure‑cooking the bourbon stillage, chemists made carbon‑rich hydrochar to create hybrid lithium‑ion supercapacitors that could store up to 25 times more energy per kilogram than conventional versions, while a second set of double‑layer devices retained almost 96 percent of their storage capacity after 10,000 charge‑discharge cycles, according to the University of Kentucky. Stillage surplus as distillery growth outstrips local feed capacity The project is driven by a simple supply‑and‑demand imbalance for stillage. Stillage, which can be used as animal feed or fertilizer, is received in liquid form and becomes difficult to ship because it is heavy and bulky. Drying it through evaporation or heating reduces its weight and volume, but the process can be costly and energy-intensive. Since there has been an increase in the number of distilleries in the region, the amount of stillage that is produced has surpassed the requirement of the farmers around those distilleries, thus causing the owners of such distilleries to look elsewhere to dump the material. Graduate student Josiel Barrios Cossio, working under chemistry professor Marcelo Guzman at the University of Kentucky, identified the problem during research on food, energy and water concerns in the state. How pressure and heat turn wet stillage into hydrochar This process is referred to as hydrothermal carbonization and Barrios Cossio explains it as working much like a pressure cooker. The stillage is introduced into a lab‑scale reactor without pre‑drying and then heated under pressure at temperatures between 180 and 250 °C, a typical operating range for hydrothermal carbonization of wet biomass. The water present in the reactor serves as a solvent and facilitates hydrolysis, dehydration, decarboxylation and aromatization of the stillage until what is left is black carbon called hydrochar. This hydrochar served as the basis for the production of two types of carbon materials. When it was heated to about 1,000 °C in a furnace, a temperature commonly used to convert hydrochar into hard carbon, the material formed a hard‑carbon structure suitable for lithium‑ion storage. This type of carbon has loosely arranged carbon layers and can be easily used for the absorption of lithium ions. Another portion of the hydrochar was mixed with potassium hydroxide and heated to about 800°C to produce activated carbon, according to the study published in Materials Advances. Building two different carbons from the same waste stream The fact that they could produce two different carbons, which have different functions, enabled the group to develop two types of electronic devices. The first is an electric double-layer supercapacitor, which can be produced using a conventional method of putting together two activated carbon electrodes with the help of a liquid electrolyte in between them. The second device, which is more unique, combines one activated carbon electrode and another hard carbon electrode doped with lithium ions and hence can be considered a hybrid lithium-ion supercapacitor, having the advantages of both a battery and a capacitor. Barrios Cossio said that the hybrid device was actually quite a surprise, as devices of such type are not easy to manufacture. This particular project had attracted experts from outside the group, as researchers from the Friedrich Schiller University Jena in Germany collaborated with the group. The research was presented at ACS Spring 2026 in Atlanta under the title “Bourbon Whiskey Waste-Derived Carbons for Electric Double Layer and Lithium-Ion Supercapacitors,” according to the American Chemical Society. There is also a peer-reviewed paper on the same topic in the journal Materials Advances: J. Barrios Cossio et al., 'Valorisation of bourbon distillery waste into single-source hybrid lithium-ion capacitors.' What the supercapacitors actually achieved The hybrid lithium-ion capacitors are the source of the headline 25× figure: the University of Kentucky reported that the devices stored up to 25 times more energy per kilogram than conventional supercapacitors. The symmetric double-layer capacitors made using the activated carbon electrodes achieved energy densities ranging from 1.9 to 23.8 Wh/kg, depending on the power density used during testing, while retaining 96 ± 2% of their initial capacitance after 10,000 charge-discharge cycles, according to the peer-reviewed Materials Advances paper. The hybrid lithium-ion capacitors, evaluated separately, achieved energy densities ranging from 48 to 135 Wh/kg at power densities of 0.215 to 22 kW/kg, according to the paper. The hybrid design paired activated carbon with hard carbon to combine capacitor-type and battery-type energy-storage behavior. As the presentation makes clear, these figures represent proof‑of‑concept results rather than a commercial product. The next stage for the team would be conducting techno-economic and life-cycle analysis to test whether such a process can be scaled up beyond laboratory settings. How this builds on Kentucky's earlier work with corn-based carbon It was not the university’s first effort to convert agricultural feedstocks into supercapacitor materials. In 2018, University of Kentucky researchers Wenxin Cao and Fuqian Yang published ‘Supercapacitors from high fructose corn syrup‑derived activated carbons’ in Materials Today Energy. They showed that hydrothermal processing followed by physical activation could convert high-fructose corn syrup into spherical activated carbon particles with a surface area of 1,473 m²/g. Using a potassium hydroxide electrolyte, symmetrical supercapacitor cells made from the carbon achieved a specific capacitance of 168 F/g and an energy density of 4.2 Wh/kg. AI Representation: Hydrochar-based electrodes show high energy storage and long-term cycling stability. Image credits: Chatgpt The earlier study showed that hydrothermal processing could also turn sugar-based feedstocks into carbon for supercapacitors, though with lower energy density. The hybrid lithium-ion capacitors, meanwhile, achieved energy densities of 48–135 Wh/kg and showed different cycling behavior, losing 17 ± 3% of their capacitance and capacity after 5,000 cycles and an additional 14 ± 2% after 10,000 cycles. What still needs to happen before this scales up It all implies that nothing like a product available for immediate manufacturing out of stillage-based supercapacitors is ready yet. This work is an academic research collaboration supported by the University of Kentucky Materials Science Research Priority Area, with additional funding from the U.S. National Science Foundation and the German Chemical Industry Fund. The published paper does not identify an industry manufacturing partner. Scaling up the process from a laboratory reactor to handling the much larger volumes of stillage generated by a commercial distillery would be a substantially different challenge from demonstrating the process in the laboratory. The composition of stillage can vary with the grains and distillation processes used by different distilleries. As the researchers utilized stillage obtained from several distilleries, a scalable production process should be able to withstand the differences in the composition of stillage. Despite these challenges, the study demonstrates that bourbon stillage can be converted into carbon materials for energy-storage devices, with the hybrid lithium-ion capacitors achieving higher energy densities than the symmetric double-layer capacitors tested in the study. Their cycling performance differed, however, so the two designs should not be described as having equal cycle life. (Catch all the US News, UK News, Canada News, International Breaking News Events, and Latest News Updates on The Economic Times.) Download The Economic Times News App to get Daily International News Updates. (Catch all the US News, UK News, Canada News, International Breaking News Events, and Latest News Updates on The Economic Times.) Download The Economic Times News App to get Daily International News Updates.